Synthesis and characterization of substituted dibenzotetraazaannulenes (DBTAAs) and DBTAA-modified polymer monoliths : implications for chemical separations
Ford, Kathleen M.
Thesis (M.S.)--Georgetown University, 2010.; Includes bibliographical references.; Text (Electronic thesis) in PDF format. Dibenzotetraazaannulenes (DBTAAs) have inspired research in a variety of areas since first being synthesized thirty years ago. Studies have investigated such topics as their electropolymerization on electrode surfaces, interactions with DNA/RNA, electrochemical activity, and catalytic capabilities. Their structural similarity to porphyrins makes them an exciting option for immobilization for the fabrication of high performance liquid chromatographic separations (HPLC) stationary phases. We report here characterization of a series of 6,17-dimethyl-8,15-diphenyl DBTAA complexes, as well as fabrication of a vinylaniline/polydivinylbenzene monolith and modification of the monolith with a styrylmethyl derivative of the nickel DBTAA complex. The monoliths have been characterized using nitrogen porosimetry, field emission electron scanning microscopy, X-ray photoelectron spectroscopy, and both small and ultrasmall angle neutron scattering. Bare and modified monoliths have been characterized using X-ray photoelectron spectroscopy. These indicate that the DBTAA complex can be immobilized on the surface and, as such, provide the basis for further investigation.
Showing items related by title, author, creator and subject.
DEVELOPMENT AND CHARACTERIZATION OF CONDUCTING POLYMER MODIFIED ELECTRODES FOR NEUROLOGICAL APPLICATIONS Kammerich, Anthony David (Georgetown University, 2011)Electrodes have the potential to be applied to neurological signal detection, neurotransmitter detection, or neurological stimulation, but there are many factors to consider. These factors include the electrochemical ...
Alkanethiolate-Protected Silver Nanoparticles and Clusters: Characterization, Synthesis Optimization and Formation Mechanism Investigation Liu, Yangwei (Georgetown University, 2016)The primary objective of this thesis research was to investigate reaction process of silver nanoparticle (Ag NP) and nanocluster synthesis; to develop facile and efficient way to synthesize small and homogeneous silver ...
Gels from Borate-Crosslinked Partially Hydrolyzed Poly(vinyl acetate)s: Characterization of Physical and Chemical Properties and Applications in Art Conservation Angelova, Lora Vihrova (Georgetown University, 2013)The formation of gel-like dispersions from borate-crosslinked, partially hydrolyzed poly(vinyl acetate)s (xPVAc, where x is the percent of hydrolysis) and their application for treatment of art is explored. It is shown ...